Synthesis of α-MoO3 Thin Sheets and Their Catalytic Behavior for Selective Oxidation of Methanol to Formaldehyde
Autor: | Nguyen H. H. Phuc, Nguyen Phuc Hoang Duy, Pham T. T. Phuong, Nguyen Manh Huan, Vo T. Tai, Luu Cam Loc |
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Rok vydání: | 2015 |
Předmět: |
Scanning electron microscope
Inorganic chemistry Formaldehyde 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences Molybdenum trioxide chemistry.chemical_compound symbols.namesake chemistry symbols Methanol 0210 nano-technology Raman spectroscopy Organometallic chemistry Nuclear chemistry Diffractometer |
Zdroj: | Catalysis Letters. 146:391-397 |
ISSN: | 1572-879X 1011-372X |
DOI: | 10.1007/s10562-015-1640-2 |
Popis: | α-MoO3 thin sheets were successfully synthesized from all commercial materials using a fast, effective and simple method and characterized by X-ray diffractometer, scanning electron microscopy, IR and Raman spectroscopy. The prepared catalyst was highly active and selective to formaldehyde formation from methanol over a wide range of reaction temperatures comparing to the commercial one. We found that the high selectivity of formaldehyde over the prepared α-MoO3 was originated from its special morphology, which had abundant exposed edges comparing to the commercial α-MoO3. Additionally, the prepared α-MoO3 showed significant stability due to its stable nature. |
Databáze: | OpenAIRE |
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