Synthesis, spectroscopic characterization, and electrochemical properties of bis[1,2-bis(5-chlorosalicylideneamino)ethanato(.mu.-oxo)manganese(IV)]

Autor: Gregory C. Dailey, Carol A. Lisek, Colin P. Horwitz
Rok vydání: 1992
Předmět:
Zdroj: Inorganic Chemistry. 31:5325-5330
ISSN: 1520-510X
0020-1669
DOI: 10.1021/ic00051a026
Popis: Reaction of the complex (5-Cl-SALEN)Mn II (5-Cl-SALEN= 1,2-bis(5-chlorosalicylideneamino)ethane), formed by electrochemical reduction of [(5-Cl-SALEN)Mn III ] + or initially synthesized in the Mn(II) form, with dioxygen in CH 3 CN produces the bis(μ-oxo) dimer [(5-Cl-SALSN)Mn IV (μ-O)] 2 .
Databáze: OpenAIRE