Synthesis, spectroscopic characterization, and electrochemical properties of bis[1,2-bis(5-chlorosalicylideneamino)ethanato(.mu.-oxo)manganese(IV)]
Autor: | Gregory C. Dailey, Carol A. Lisek, Colin P. Horwitz |
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Rok vydání: | 1992 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 31:5325-5330 |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/ic00051a026 |
Popis: | Reaction of the complex (5-Cl-SALEN)Mn II (5-Cl-SALEN= 1,2-bis(5-chlorosalicylideneamino)ethane), formed by electrochemical reduction of [(5-Cl-SALEN)Mn III ] + or initially synthesized in the Mn(II) form, with dioxygen in CH 3 CN produces the bis(μ-oxo) dimer [(5-Cl-SALSN)Mn IV (μ-O)] 2 . |
Databáze: | OpenAIRE |
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