Synthesis of Pentane-1,5-dialdehydes
| Autor: | Gwk Cavill, DH Solomon |
|---|---|
| Rok vydání: | 1960 |
| Předmět: | |
| Zdroj: | Australian Journal of Chemistry. 13:121 |
| ISSN: | 0004-9425 |
| DOI: | 10.1071/ch9600121 |
| Popis: | A general method for the synthesis of alkylpentane-1,5-dialdehydes is described. The appropriately substituted cyclohexanone is oxidized with lead tetra-acetate in benzene solution, and the resultant 2,6-diacetoxycyclohexanone is reduced (lithium aluminium hydride) to the cyclohexane-1,2,3-triol. Fission of the trio1 with sodium periodate yields the pentane-1,5-dialdehyde. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|