Comments on the linear relation between reaction rate and affinity

Autor:	Juan Carlos Gottifredi, Daniel G. Löffler, Michel Boudart
Rok vydání:	1985
Předmět:	Order of reaction Cyclohexane Organic Chemistry Thermodynamics Photochemistry Rate-determining step Biochemistry Inorganic Chemistry Reaction rate chemistry.chemical_compound Reaction rate constant chemistry Elementary reaction Dehydrogenation Physical and Theoretical Chemistry Stoichiometry
Zdroj:	International Journal of Chemical Kinetics. 17:1119-1123
ISSN:	0538-8066
DOI:	10.1002/kin.550171008
Popis:	In the case of catalytic dehydrogenation of cyclohexane, the linear relation between reaction rate and affinity holds at an appreciable distance away from equilibrium on both sides. In fact, in order to explain this observation, it is necessary to invoke a high value of three for the stoichiometric number of the rate determining step. This in turn can be explained by a reasonable mechanism for the reaction.
Databáze:	OpenAIRE
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