Ionic Liquid–Promoted Stereoselective Synthesis of (Z)‐Vinyl Bromides by [bmIm]OH under Organic Solvent–Free Conditions: A Green Approach

Autor:	Brindaban C. Ranu, Jhinuk Gupta, Subhash Banerjee
Rok vydání:	2007
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Base (chemistry) chemistry Organic solvent Organic Chemistry Ionic liquid Organic chemistry Hydroxide Stereoselectivity Organic solvent free
Zdroj:	Synthetic Communications. 37:2869-2876
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397910701471386
Popis:	A simple and easily accessible ionic liquid, 1‐butyl‐3‐methylimidazolium hydroxide ([bmIm]OH), has been demonstrated as an efficient promoter and reaction medium for the highly stereoselective synthesis of (Z)‐vinyl bromides by the debrominative decraboxylation of dibrominated α,β‐unsaturated carboxylic acids in high yields. The reaction does not require either a conventional base or an organic solvent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::49392d66b4e17ae593d800a352c8bd71 https://doi.org/10.1080/00397910701471386 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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