Synthesis of 1,10-decanediol diacetate and 1-decanol acetate from furfural

Autor:	Yao Fu, Chen-Qiang Deng, Jin Deng, Qin-Zhu Jiang
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Furoin Acetic acid 1-Decanol chemistry Yield (chemistry) Environmental Chemistry Organic chemistry Benzoin condensation Furfural Pollution Hydrodeoxygenation Catalysis
Zdroj:	Green Chemistry. 23:2169-2176
ISSN:	1463-9270 1463-9262
Popis:	A green and efficient method was developed for upgrading furfural to 1,10-decanediol diacetate and 1-decanol acetate. 92% yield of the acetates was obtained through the tandem benzoin condensation and hydrodeoxygenation reaction. During the benzoin condensation, furfural was catalyzed into furoin in a quantitative yield by the immobilized NHC catalyst under solvent-free conditions. After dissolving the furoin intermediate in acetic acid, the Sc(OTf)3 and Pd/C catalytic system was introduced for hydrodeoxygenation. The effects of reaction factors have been investigated in detail and the hydrodeoxygenation process has been explored by 1H-NMR and GC-MS.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4935d258089c44f438c28e8c198ba6ac https://doi.org/10.1039/d1gc00227a Zobrazit plný text záznamu