Synthesis of 1,10-decanediol diacetate and 1-decanol acetate from furfural
Autor: | Yao Fu, Chen-Qiang Deng, Jin Deng, Qin-Zhu Jiang |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Green Chemistry. 23:2169-2176 |
ISSN: | 1463-9270 1463-9262 |
Popis: | A green and efficient method was developed for upgrading furfural to 1,10-decanediol diacetate and 1-decanol acetate. 92% yield of the acetates was obtained through the tandem benzoin condensation and hydrodeoxygenation reaction. During the benzoin condensation, furfural was catalyzed into furoin in a quantitative yield by the immobilized NHC catalyst under solvent-free conditions. After dissolving the furoin intermediate in acetic acid, the Sc(OTf)3 and Pd/C catalytic system was introduced for hydrodeoxygenation. The effects of reaction factors have been investigated in detail and the hydrodeoxygenation process has been explored by 1H-NMR and GC-MS. |
Databáze: | OpenAIRE |
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