Pd/C-mediated depropargylation of propargyl ethers/amines in water

Autor: S. Bhavani, D. Rambabu, Nalivela Kumara Swamy, Manojit Pal, M. V. Basaveswara Rao
Rok vydání: 2013
Předmět:
Zdroj: Tetrahedron Letters. 54:1169-1173
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2012.12.093
Popis: Propargyl ethers and amines are effectively depropargylated to the parent alcohols or amines via a C−O/C−N bond cleavage catalyzed by 10% Pd/C in water. This simple, facile, and inexpensive methodology could be utilized for the selective removal of propargyl groups from a variety of aryl ethers and amines.
Databáze: OpenAIRE