Pd/C-mediated depropargylation of propargyl ethers/amines in water
Autor: | S. Bhavani, D. Rambabu, Nalivela Kumara Swamy, Manojit Pal, M. V. Basaveswara Rao |
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Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 54:1169-1173 |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2012.12.093 |
Popis: | Propargyl ethers and amines are effectively depropargylated to the parent alcohols or amines via a C−O/C−N bond cleavage catalyzed by 10% Pd/C in water. This simple, facile, and inexpensive methodology could be utilized for the selective removal of propargyl groups from a variety of aryl ethers and amines. |
Databáze: | OpenAIRE |
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