Rearrangement of bis(trimethylsilyl)silylene (Me3Si)2Si in the gas phase; new silylene-to-silylene interconversions

Autor:	Peter P. Gaspar, Bruce H. Cohen, Yue-Shen Chen
Rok vydání:	1980
Předmět:	Trimethylsilyl Organic Chemistry Silylene Photochemistry Biochemistry Medicinal chemistry Silane Gas phase Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Materials Chemistry Physical and Theoretical Chemistry Pyrolysis
Zdroj:	Journal of Organometallic Chemistry. 195:C5-C8
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)93393-x
Popis:	When bis(trimethylsilyl)silylene, (Me 3 Si) 2 Si, is generated in the gas phase by flow pyrolysis of methoxytris(trimethylsilyl)silane, (Me 3 Si) 3 SiOMe, or chlorotris(trimethylsilyl)silane, (Me 3 Si) 3 SiCl, the dominant reaction is rearrangement, producing as the major product in ca. 60% yield 1,1,4,4-tetramethyl-1,2,4-trisilacyclopentane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4920f3dbba341022769993df4911af13 https://doi.org/10.1016/s0022-328x(00)93393-x Zobrazit plný text záznamu