Thermodynamic evaluation of the Fe–Zn system

Autor: Nai-Yong Tang, Xuping Su, Jim M. Toguri
Rok vydání: 2001
Předmět:
Zdroj: Journal of Alloys and Compounds. 325:129-136
ISSN: 0925-8388
DOI: 10.1016/s0925-8388(01)01273-7
Popis: The Fe–Zn binary system has been evaluated using the calculation of phase diagram (CALPHAD) method. In the evaluation, the ζ (FeZn13) phase is treated as a stoichiometric compound because of its rather narrow solution range, and the δ (FeZn10), the Γ1 (Fe5Zn21) and the Γ (Fe3Zn10) phases are described using sublattice models because they all have a relatively wide homogeneity range. A consistent set of optimized thermodynamic parameters describing the individual phases of this system has been derived, leading to a better fit between the calculated results and the experimental data reported in the literature. The reproduction of the thermochemical and phase diagram information is reported in a series of figures and tables.
Databáze: OpenAIRE