Novel copper(I) complex of 2,5-Bis(2-pyridyl)phosphole: Synthesis, Characterization, Catalytic Activity and DFT Calculations

Autor:	Edward E. Ávila, Mora, Garcia Garfido Jm, Rivera-Campos R, Yomaira Otero, Andreas Reiber, Oliveros D, Franmerly Fuentes, Guaramato J
Rok vydání:	2021
Předmět:	Base (group theory) chemistry.chemical_compound Crystallography Materials science chemistry Phosphole chemistry.chemical_element Tetrahedral molecular geometry Copper Dynamic equilibrium Catalysis Characterization (materials science)
Popis:	A copper(I) complex [CuCl{k1(P)-1a}{k2(P,N)-1a}] (1a = 2,5-bis(2-pyridyl)-1-phenylphosphole) with pseudo tetrahedral geometry was synthesized. In solution, 1a displays a hemilabile behaviour leading to a dynamic equilibrium between four and three-coordinate specie. Its catalytic potential was tested in synthesis of propargylamines and 1,2,3-triazoles via three-component reactions. Experimental results discussed on base to DFT calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::49033367de9346a7bab63bab948b29a7 https://doi.org/10.26434/chemrxiv.13634885.v1 Zobrazit plný text záznamu