ChemInform Abstract: Stereoselectivities in the Coupling Reaction Between Silylated Pyrimidine Bases and 1-Halo-2,3-dideoxyribose

Autor:	Takashi Ebata, Katsuya Matsumoto, Koshi Koseki, Hajime Matsushita, Yoshitake Naoi, Hiroshi Kawakami, Kazuo Itoh
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chloroform Anomer chemistry Pyrimidine Tertiary amine Stereochemistry Stereoselectivity General Medicine Selectivity Coupling reaction
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199114292
Popis:	Coupling reactions between 1-chloro-2,3-dideoxyribose and silylated pyrimidines have been examined from the point of stereoselectivity. When the reaction was carried out in chloroform, the selectivity was in the anomeric ratio of α:β=4:6. On the other hand, the presence of tertiary amine raises the selectivity to α:β=3:7
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::48f9646cd5b0d160e1f6da662b188cc8 https://doi.org/10.1002/chin.199114292 Zobrazit plný text záznamu Plný text