Platinum-Catalyzed the Rearrangement of Propargylic Esters and C—H Bond Functionalization Adjacent to the Nitrogen of Tertiary Amines

Autor: XF Xia, YM Liang, LH Li
Rok vydání: 2013
Předmět:
Zdroj: Chinese Journal of Organic Chemistry. 33:675
ISSN: 0253-2786
DOI: 10.6023/cjoc201301019
Popis: Our recent progress in platinum-catalyzed the rearrangement of propargylic esters and C-H bond functionalization adjacent to the nitrogen of tertiary amines is summaried The effect of the design of the substrates and additives on these reactions is described, and the mechanisms of these reactions are also discussed. At the same time, the first oxidant-free cross-dehydrogenative coupling (CDC) reaction under platinum-catalysis is proposed.
Databáze: OpenAIRE