Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co2(BP)(tqa)2](PF6)2 (H4BP = 4,4′-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties
| Autor: | Yusaku Suenaga, Takuto Mibu, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa, Kunihisa Sugimoto |
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| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Dalton Transactions. 50:9833-9841 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/d1dt00995h |
| Popis: | [Co2(BP)(bpqa)2](PF6)2 shows evidence of temperature dependence of the charge distribution, displaying a thermally induced valence tautomeric transition from the lsCoIII-[Cat–Cat]-lsCoIII to hsCoII-[Sq–Sq]-hsCoII in both solid and solution states. |
| Databáze: | OpenAIRE |
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