A new rigid ligand anthraquinone-1,4,5,8-tetracarboxylic acid (H4AQTC) and its two new porous metal-organic frameworks: Syntheses, structures and properties

Autor:	Changsheng Lu, Qing-Jin Meng, Yang-Mei Liu, Fang-Ming Wang, Rui He
Rok vydání:	2010
Předmět:	Porous metal Langmuir Materials science Ligand Maleic anhydride Anthraquinone Inorganic Chemistry chemistry.chemical_compound Adsorption chemistry Polymer chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Porosity Porous medium
Zdroj:	Inorganic Chemistry Communications. 13:1375-1379
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2010.06.046
Popis:	A new rigid multicarboxylates anthraquinone-1,4,5,8-tetracarboxylic acid (H4AQTC) was synthesized based on a modified synthetic procedure from 2,5-dimethylfuran and maleic anhydride. This rigid ligand can be widely utilized to construct rigid porous MOFs which may be candidates of porous materials. Two new rigid porous MOFs {[Cd(AQTC)0.5(H2O)3]·H2O}n (1) and {[Ni(AQTC)0.5(BPY)0.5(H2O)3]·2H2O}n (2) based on this rigid ligand are reported (BPY = 4,4'-bpy). The adsorption properties of complexes 1 and 2 are investigated, and the Langmuir surface areas are measured to be 43.25 m2/g and 389.14 m2/g.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::48e21da35ae471d5b7357dc2b664d8e4 https://doi.org/10.1016/j.inoche.2010.06.046 Zobrazit plný text záznamu Full Text from ScienceDirect