Acylalkylation of Arynes Generated from o-Iodoaryl Triflates with Hydrosilanes and Cesium Fluoride

Autor:	Yu Nakamura, Keisuke Uchida, Mai Minoshima, Suguru Yoshida, Takamitsu Hosoya
Rok vydání:	2021
Předmět:	010405 organic chemistry Chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry Aryne 0104 chemical sciences chemistry.chemical_compound Caesium Physical and Theoretical Chemistry Triethylsilane Fluoride
Zdroj:	Organic Letters. 23:1868-1873
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.1c00279
Popis:	An efficient method to generate aryne intermediates from o-iodoaryl triflates triggered by triethylsilane and cesium fluoride is disclosed. This method realized the acylalkylation of arynes using e...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::48cd7c72f8efec5f4f1a684ce13324d6 https://doi.org/10.1021/acs.orglett.1c00279 Zobrazit plný text záznamu