N-Methylimidazole Mediated Chemistry of Transition Metal Phenylthiolates. The Isolation of the Perthiolate Salts [M(N-MeIm)6](S2Ph)2

Autor:	Partha P. Paul, Somanath Dev, Ulrike Krautscheid, Thomas B. Rauchfuss, Scott R. Wilson, Harald Krautscheid
Rok vydání:	1993
Předmět:	Chemistry Stereochemistry General Chemistry Crystal structure Medicinal chemistry Metal chemistry.chemical_compound Transition metal N-methylimidazole visual_art X-ray crystallography visual_art.visual_art_medium Imidazole Molecule Dissolution
Zdroj:	Zeitschrift für Naturforschung B. 48:653-658
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-1993-0515
Popis:	Salts of the composition [M(N-MeIm)6](SPh)2 (M = Mn, Ni; N-MeIm = N-methylimidazole) were prepared by dissolution of the metal powders with N-MeIm solutions of Ph2S2. X-ray crystallographic examination established that these salts indeed feature uncoordinated PhS-. The salts [M(N-McIm)6](SPh)2 (M = Mn, Ni) react with S8 to give [M(N-MeIm)6]S8 via the intermediacy of the perthiolate salts [M(N-MeIm)6](S2Ph)2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::48cc9113878203ee5ff9261d606b85c3 https://doi.org/10.1515/znb-1993-0515 Zobrazit plný text záznamu