Preparation, spectral, structural and hirshfeld surface analysis of a new organic-inorganic compound (C5H7N2).[ZnCl3(C5H6N2)]
| Autor: | Hicham El Hamdani, Lahcen El Ammari, Mohamed Saadi, Mohamed EL-Amane |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
010405 organic chemistry
Chemistry Hydrogen bond Organic Chemistry Stacking Supramolecular chemistry Infrared spectroscopy Crystal structure Triclinic crystal system 010402 general chemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Crystallography Molecule Thermal analysis Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 1229:129835 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2020.129835 |
| Popis: | Single crystals of organic-inorganic hybrid compound (C5H7N2).[ZnCl3(C5H6N2)] was synthesized by slow evaporation method at room temperature and characterized byX-ray diffraction analysis, UV-visible, infrared spectroscopy (FTIR) and thermal analysis (TGA and DTA).This complex crystallizes in the triclinic system, space group P 1 ¯ . The unit cell parameters are a = 8.164 (4) A, b = 9.196 (5), A, c = 10.892 (6) A, α = 89.25 (2)°, β = 86.23 (2)°, ɤ = 63.87 (2)°, Z = 2 and V =732.5 (6) A3. The asymmetric unit of the title compound containsa distorted tetrahedral [ZnCl3(C5H6N2)]−1 anion and one protonated 2-Aminopyridinium cation. The Zn(II) ion is coordinated by three chloro ligands (Cl) and one nitrogen belonging to 2-aminopyridine ligand building a distorted tetrahedron.The supramolecular compound exhibits a three-dimensional solid state structure resulting from the interconnection of molecules through N–H···Cl, C–H···Cl hydrogen bonds and π–π stacking interactions. |
| Databáze: | OpenAIRE |
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