Pd complexes containing non-symmetrical diphosphines in the terpolymerization of ethene, propene and carbon monoxide

Autor:	Giambattista Consiglio, Antonella Leone, Sebastian Gischig
Rok vydání:	2007
Předmět:	Process Chemistry and Technology Kinetics Cationic polymerization chemistry.chemical_element Nuclear magnetic resonance spectroscopy Photochemistry Catalysis Propene chemistry.chemical_compound chemistry Diphosphines Polymer chemistry Physical and Theoretical Chemistry Carbon monoxide Palladium
Zdroj:	Journal of Molecular Catalysis A: Chemical. 265:98-108
ISSN:	1381-1169
Popis:	The preparation and the characterization of palladium(II) neutral dichloro complexes [PdCl2(P^P′)] 1a–d and cationic disolvento complexes [Pd(P^P′)(H2O)2](OTf)2 3a–d containing non-symmetrical Cs-symmetrical diphosphines are reported. Terpolymerization of ethene, propene and carbon monoxide was carried out with the catalyst precursors 3a–d. In the test of each catalyst precursor the ethene pressure was systematically increased, while the propene concentration and carbon monoxide pressure were kept constant. The produced terpolymers were characterized by means of 1H and 13C NMR spectroscopy. The catalytic activity of the systems tested is discussed. The structure of the produced terpolymers is analyzed via NMR spectroscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::48574b588fce2f615cab0de04216ea69 https://doi.org/10.1016/j.molcata.2006.09.051 Zobrazit plný text záznamu Full Text from ScienceDirect