Experimental and Theoretical Evidence of an SN2-Type Mechanism for Dissociation of B−N Coordination Bonds in 2,6-Bis((dimethylamino)methyl)phenylborane Derivatives1

Autor:	Michinori Ōki, Mitsuhiro Asakura, Shinji Toyota, and Hiroshi Ikeda, Tadahiro Futawaka
Rok vydání:	1998
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Organic Chemistry SN2 reaction Physical and Theoretical Chemistry Borane Dissociation (chemistry)
Zdroj:	Organometallics. 17:4155-4163
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om9803974
Popis:	To distinguish between dissociation of a B−N coordination bond by SN1- and SN2-type mechanisms, two series of 1,3,2-dioxaborolanes (boronates) and BEt2 (borane) complexes carrying a 2,6-bis((dimeth...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4847d332fb04d49f6096780832f8fa0f https://doi.org/10.1021/om9803974 Zobrazit plný text záznamu