Solubility measurements for the CH 4 + C 2 H 6 + H 2 O system under hydrate-liquid-vapour equilibrium

Autor:	Phillip Servio, Francis Lang
Rok vydání:	2015
Předmět:	Future studies Equilibrium conditions Clathrate hydrate Energy Engineering and Power Technology Thermodynamics Solubility equilibrium Geotechnical Engineering and Engineering Geology Mole fraction Methane chemistry.chemical_compound Fuel Technology chemistry Solubility Hydrate
Zdroj:	Journal of Natural Gas Science and Engineering. 26:130-134
ISSN:	1875-5100
DOI:	10.1016/j.jngse.2015.06.002
Popis:	Liquid and gas mole fractions were obtained at three-phase H-Lw-V equilibrium for the CH 4 + C 2 H 6 + H 2 O system at experimental conditions ranging from 275.1 to 279.1 K and 0.76–2.87 MPa. To ensure the system reached equilibrium while sampling, gaseous mole fractions were compared to literature values and were found to correspond. The solubility of both methane and ethane along isotherms is reported at various pressures. The effect of thermodynamic parameters on equilibrium liquid mole fractions can be observed. Additionally, structure transitions between sI and sII were found to influence solubility trends. While scarce in literature, experimentally obtained liquid mole fractions at three-phase equilibrium conditions provide further insights into multicomponent gas hydrate system properties and establish a solid foundation for future studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4824ee74e8f67284e50089855a3d4385 https://doi.org/10.1016/j.jngse.2015.06.002 Zobrazit plný text záznamu Full Text from ScienceDirect