ChemInform Abstract: Gold-Facilitated '6-Exo-dig' Intramolecular Cyclization of 2-[(2-Nitrophenyl)ethynyl]phenylacetic Acids: General Access to 5H-Benzo[b]carbazole-6,11-diones
Autor: | Ricardo A. Tapia, Francisco J. Reboredo, Cristian O. Salas, Juan C. Estevez, Ramón J. Estévez |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 41 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.201016101 |
Popis: | The preliminary results of a regiospecific synthesis of ( Z)-1-(2-nitrobenzylidene)isochroman-3-onesby gold(I)-catalyzed cycloisomerization of phenylethynylacetic acidsunder mild conditions is described. These novel lactones provedto be suitable starting materials for a new, general access to 5 H-benzo[ B]carbazole-6,11-diones. |
Databáze: | OpenAIRE |
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