ChemInform Abstract: Gold-Facilitated '6-Exo-dig' Intramolecular Cyclization of 2-[(2-Nitrophenyl)ethynyl]phenylacetic Acids: General Access to 5H-Benzo[b]carbazole-6,11-diones

Autor: Ricardo A. Tapia, Francisco J. Reboredo, Cristian O. Salas, Juan C. Estevez, Ramón J. Estévez
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 41
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.201016101
Popis: The preliminary results of a regiospecific synthesis of ( Z)-1-(2-nitrobenzylidene)isochroman-3-onesby gold(I)-catalyzed cycloisomerization of phenylethynylacetic acidsunder mild conditions is described. These novel lactones provedto be suitable starting materials for a new, general access to 5 H-benzo[ B]carbazole-6,11-diones.
Databáze: OpenAIRE