Bis(1,1,1,3,5,5,5-heptafluoro-4-iminopent-2-ene-2-aminato)copper(ii) — a new metal-containing matrix in the design of heterospin systems

Autor:	V. I. Ovcharenko, O. N. Chupakhin, L. V. Saloutina, A. S. Bogomyakov, Galina V. Romanenko, Evgeny V. Tretyakov, T. I. Filyakova, V. N. Charushin, S. V. Fokin, Viktor I. Saloutin
Rok vydání:	2011
Předmět:	Nitroxide mediated radical polymerization Hydrogen Hydrogen bond Chemistry Radical Inorganic chemistry Supramolecular chemistry chemistry.chemical_element General Chemistry Copper Metal visual_art Polymer chemistry visual_art.visual_art_medium Ene reaction
Zdroj:	Russian Chemical Bulletin. 60:816-823
ISSN:	1573-9171 1066-5285
Popis:	The first heterospin compounds based on bis(1,1,1,3,5,5,5-heptafluoro-4-iminopent-2-ene-2-aminato)copper(ii) (CuL2) and nitronyl nitroxide radicals, 2-R-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyls (NIT-R, where R = H, Me, Ph, and 1-methylpyrazol-4-yl), were synthesized and structurally characterized. An important peculiarity of the structure of synthesized solid phases is the formation of a supramolecular structure due to hydrogen bonds between the oxygen atoms of the nitronyl nitroxide fragments of NIT-R and the hydrogen atoms of the NH groups of CuL2.
Databáze:	OpenAIRE
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