A new synthetic route to [MF(μ-F)(CO)3]4 (M=Ru, Os) and their reactivity with P(C6H4-4-X)3 (X=OCH3, OH) and P(C6H4-2-OH)3
| Autor: | John H. Holloway, Eric G. Hope, Roger Nassar, John Fawcett, Karl S. Coleman |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
Chemistry
Ligand Organic Chemistry Inorganic chemistry chemistry.chemical_element Triosmium dodecacarbonyl Crystal structure Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Tetramer Anhydrous Fluorine Environmental Chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Phosphine |
| Zdroj: | Journal of Fluorine Chemistry. 112:185-189 |
| ISSN: | 0022-1139 |
| Popis: | The reaction of [M 3 (CO) 12 ] (M=Ru, Os) with elemental fluorine in anhydrous HF offers a clean, convenient route to [MF(μ-F)(CO) 3 ] 4 . This tetramer reacts with Tris– ortho -hydroxyphenyl phosphine, with the elimination of HF, to give a new, metal-bound, trihapto ( η 3 -P,O,O) ligand. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect