ChemInform Abstract: Dioxirane Oxidations of Compounds Other than Alkenes

Autor:	Waldemar Adam, Cong Gui Zhao, Kavitha Jakka
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Silanes Double bond Heteroatom chemistry.chemical_element General Medicine Sulfur chemistry.chemical_compound chemistry Dioxirane Organic chemistry Lone pair Deoxygenation Group 2 organometallic chemistry
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200912255
Popis:	Epoxidations, heteroatom oxidations, and Y-H insertions constitute the best investigated oxidations by dioxiranes. This article concerns epoxidation of the double bonds in the cumulenes, such as allenes, acetylenes, and arenes; the oxidation of heteroatom functionalities, mainly lone pairs on sulfur, on nitrogen, and on oxygen as the deoxygenation of N-oxides; the oxidation of C = Y functionalities, Y-H insertions such as in C-H alkanes, and Si-H silanes; and the oxidation of organometallic substrates including metal and ligand-sphere oxidation. Keywords: Dioxirane oxidations; Allenes; Alkynes; Arenes; Heteroatom substrates; Alkanes; Silanes; Organometallic compounds; Mechanisms; Nitrogen; Sulfur; Selenium; Phosphorus; Oxygen; Halogens; Method comparisons; Experimental procedures
Databáze:	OpenAIRE
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