Natural physical aging in glassy As–Se: A comparative study of chaotic behavior with enhanced results analysis

Autor:	Roman Golovchak, Andrzej Kozdras, I. Kusbeyzi Aybar, Orhan Ozgur Aybar, V. Balitska, Yani Skarlatos, Avadis Hacinliyan, Oleh Shpotyuk
Rok vydání:	2014
Předmět:	Thermodynamic equilibrium Chemistry Chaotic Thermodynamics Condensed Matter Physics Electronic Optical and Magnetic Materials Fractal Phase space Attractor Materials Chemistry Ceramics and Composites Detrended fluctuation analysis Relaxation (physics) Glass transition
Zdroj:	Journal of Non-Crystalline Solids. 386:8-13
ISSN:	0022-3093
DOI:	10.1016/j.jnoncrysol.2013.11.022
Popis:	Theory of chaos is shown to be adequately applied to analyze kinetics of natural physical aging revealed in structural relaxation of Se-rich As–Se glasses below glass transition. Kinetics of enthalpy losses induced by prolonged storage in natural conditions is used to determine phase space reconstruction parameters. The observed chaotic behavior (involving chaos and fractal consideration such as detrended fluctuation analysis, attractor identification using phase space representation, delay coordinates, mutual information, and false nearest neighbors) reconstructed via TISEAN is treated within potential energy landscape as diversity of multiple transitions between different basins–metabasins towards more thermodynamically equilibrium state, minimizing the free energy of the system. Natural physical aging, facilitates further atomic shrinkage of the glass backbone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47bc6ed0b09398bbbacfceefabf4e8fc https://doi.org/10.1016/j.jnoncrysol.2013.11.022 Zobrazit plný text záznamu Full Text from ScienceDirect