Synthesis of Cu(II) aminoalkoxide complexes and their unusual thermolysis to Cu(0)

Autor:	Minchan Kim, Kiwhan Sung, Sun Sook Lee, Sang Man Koo, Chang Gyoun Kim, Hong Suk Jang, Jung Woo Park, Taek-Mo Chung, Yunsoo Kim
Rok vydání:	2004
Předmět:	Fluorine free Chemistry Inorganic chemistry Thermal decomposition chemistry.chemical_element Crystal structure Viscous liquid Copper Inorganic Chemistry Metal Elimination reaction visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry Communications. 7:463-466
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2003.12.022
Popis:	The “fluorine free” Cu(II) aminoalkoxide complexes Cu(OCMe2CH2NR2)2 (R=Me(I), Et(II)) are synthesized and characterized as a low melting solid (I) and a viscous liquid (II). The complexes are thermally decomposed at below 200 °C to produce metallic copper by unusual γ-hydrogen elimination reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47b01d35312f45ecbfb947f5ef895e0b https://doi.org/10.1016/j.inoche.2003.12.022 Zobrazit plný text záznamu Full Text from ScienceDirect