O,N-Chelated germanium, tin and lead compounds containing 2-[N,N-(dimethylamino)methyl]phenolate as ligand

Autor:	Zdeňka Padělková, Martin Novotný, Aleš Růžička, Jaroslav Holeček
Rok vydání:	2013
Předmět:	Ligand Stereochemistry Dimer Organic Chemistry Solid-state chemistry.chemical_element Germanium Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Intramolecular force Materials Chemistry Chelation Physical and Theoretical Chemistry Tin
Zdroj:	Journal of Organometallic Chemistry. 733:71-78
ISSN:	0022-328X
Popis:	Thirteen organotin(IV) and low valent complexes of group 14 (Ge, Sn, Pb) containing LNO ligand(s) (where LNO is 2-(N,N-dimethylaminomethyl)phenolate) were synthesized and its structure described by NMR techniques in solution and X-ray techniques in the solid state (for L2NOSnPh2, L2NOSnCl2, L2NOGe and LNOSnCl which forms a dimer). Structures and properties of prepared species have been compared with previously published germanium and tin compounds containing –OCH2CH2NMe2 as O,N- or LCN (where LCN is 2-(N,N-dimethylaminomethyl)phenyl) as C,N-chelating ligands. The solid state structures containing LNO ligand(s) reveal much stronger intramolecular N → Sn coordination than complexes containing latter two ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47aa2854bab583a2feead2ab102e115d https://doi.org/10.1016/j.jorganchem.2013.02.033 Zobrazit plný text záznamu Full Text from ScienceDirect