Identification of an Asymmetric Pauson−Khand Precatalyst

Autor:	Susan E. Gibson, Jennifer A. Loch, Jonathan W. Steed, Sara E. Lewis, Tozer Matthew John
Rok vydání:	2003
Předmět:	Inorganic Chemistry chemistry.chemical_compound Computational chemistry Chemistry Organic Chemistry Organic chemistry Physical and Theoretical Chemistry Mixing (physics) BINAP Catalysis
Zdroj:	Organometallics. 22:5382-5384
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om0341606
Popis:	X-ray crystallographic analysis of red crystals formed on mixing octacarbonyldicobalt(0) and BINAP, combined with NMR evidence obtained from a catalytic asymmetric Pauson−Khand reaction, suggests that this complex is a precatalyst to this reaction and leads to a new hypothesis for the role of axially chiral diphosphanes in the catalytic asymmetric Pauson−Khand reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47a17fa0d5a10251d848aa98c9f83717 https://doi.org/10.1021/om0341606 Zobrazit plný text záznamu