Copper(II) complexes with chiral reduced Schiff bases: Helical self-assembly via intermolecular C–H⋯O interactions

Autor:	Sunirban Das, Pallepogu Raghavaiah, Vamsee Krishna Muppidi, Samudranil Pal
Rok vydání:	2007
Předmět:	Chemistry Stereochemistry Intermolecular force Supramolecular chemistry Space group chemistry.chemical_element Crystal structure Copper Inorganic Chemistry Crystallography Materials Chemistry Self-assembly Physical and Theoretical Chemistry Superstructure (condensed matter)
Zdroj:	Inorganic Chemistry Communications. 10:234-238
ISSN:	1387-7003
Popis:	Copper(II) complexes having the general formula [Cu(Ln)2] with the N,O-donor reduced Schiff bases N-(2-hydroxy-5-X-benzyl)-(R)-α-methylbenzylamine and N-(2-hydroxy-5-X-benzyl)-(S)-α-methylbenzylamine (X = Cl and Br) (HLn) are described. These chiral complexes crystallize in the noncentrosymmetric P212121 (X = Cl) and P21 (X = Br) space groups. In each case, self-assembly via intermolecular C–H⋯O interaction leads to a supramolecular helical superstructure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47981df913185e019142477ecabd6b51 https://doi.org/10.1016/j.inoche.2006.10.011 Zobrazit plný text záznamu Full Text from ScienceDirect