Synthesis and properties of some Rh(I) catalytic complexes with dinitrogen ligands derived from 5-Pyrido-1,4-benzodiazepin-4-ones

Autor:	Predrag Cudic, Zlata Raza, Branimir Klaić, Vitomir Šunjić, Dragan Šepac
Rok vydání:	1991
Předmět:	chemistry.chemical_compound Denticity chemistry Cyclohexane Ligand Catalytic complex Stereochemistry Organic Chemistry Drug Discovery chemistry.chemical_element Biochemistry Nitrogen Catalysis
Zdroj:	Tetrahedron. 47:5295-5308
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)87141-6
Popis:	A series of bidentate nitrogen ligands (3–8), and their [Rh (I) (NBD) (N-N)] ClO4 complexes 11–14 (NBD-norbornadiene, N-N-dinitrogen ligand) were prepared. Conformational properties and stability of 4 and its catalytic complex 12 were reported. Catalytic activity of complexes 11 and 12 in hydrogenation of cyclohexane is compared with 22, a complex that contains 2,2′-bipyridyl as the “standard” ligand. Chiroptical data of chiral ligands 5,6 and their Rh(I) complexes 13,14 are reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::47949fb97cbe167aff2bed490643187f https://doi.org/10.1016/s0040-4020(01)87141-6 Zobrazit plný text záznamu