A dicopper(I) complex and its oxygenation chemistry using a dinucleating ligand with a pendant alkene group

Autor:	Indrajit Sanyal, Kenneth D. Karlin, Narasappa Narasimha Murthy
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Tetracoordinate Stereochemistry Chemistry Alkene Ligand Inorganic Chemistry Metal Group (periodic table) visual_art Polymer chemistry visual_art.visual_art_medium Reactivity (chemistry) Chelation Amine gas treating Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 32:5330-5337
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00075a061
Popis:	A dicopper(I) complex with new dinucleating ligand has been synthesized and structurally characterized and its reactivity with dioxygen investigated. The N3OR 1 ligand contains two tridentate PY2 (PY2=bis[2-(2-pyridyl)ethyl]amine) chelating groups with connecting group possessing an appended cinnamoyl group. An X-ray structure of [Cu 2 (N3OR 1 )](PF 6 ) 2 (1) reveals unsymmetrical coordination of Cu(I) ions; one metal ion is three-coordinate, exibiting typical ligation to the PY2 unit, while the other is tetracoordinate, also binding the cinnamoyl alkene group
Databáze:	OpenAIRE
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