Microstructure and mechanical properties of a polyethylene/polydimethylsiloxane composite prepared using supercritical carbon dioxide
| Autor: | Shoichiro Yano, Yoshio Muroga, Toshiki Hagiwara, Toru Hoshi, Takashi Sawaguchi, Rui Zhu |
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| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Materials science Supercritical carbon dioxide Polymers and Plastics Polydimethylsiloxane Composite number General Chemistry Polymer Polyethylene Supercritical fluid Surfaces Coatings and Films Crystallinity chemistry.chemical_compound chemistry Materials Chemistry In situ polymerization Composite material |
| Zdroj: | Journal of Applied Polymer Science. 127:3388-3394 |
| ISSN: | 0021-8995 |
| DOI: | 10.1002/app.37541 |
| Popis: | A polymer composite of polyethylene (PE) and polydimethylsiloxane (PDMS) was prepared using supercritical carbon dioxide despite the two polymers usually being immiscible and possessing a phase-separated morphology. This article reports in detail the preparation, microstructure, crystallinity, and mechanical properties of the resulting PE/PDMS composite. The formation mechanism of the PE/PDMS composite consisted of supercritical impregnation of an octamethylcyclotetrasiloxane (D4) monomer and an initiator into a PE substrate followed by in situ polymerization within the substrate. Differential scanning calorimetry, wide-angle X-ray diffraction, and small-angle X-ray scattering measurements showed that PE and PDMS were blended at the nanometer level. The PDMS generated in the amorphous region of PE did not affect its crystallinity. Dynamic viscoelastic analyses and tensile tests were used to measure the mechanical properties of the composites including storage and Young's modulus, fracture stress, and strain. These properties were found to depend on the composition of the composite. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
| Databáze: | OpenAIRE |
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