Titanocene(II)-promoted desulfurizative tertiary alkylation of 1,3-bis(phenylthio)alk-1-enes and β,γ-unsaturated thioacetals

Autor:	Naoki Nozaki, Takeshi Takeda, Naoko Saeki, Tooru Fujiwara
Rok vydání:	1999
Předmět:	chemistry.chemical_classification chemistry Organic Chemistry Drug Discovery chemistry.chemical_element Organic chemistry Alkylation Biochemistry Medicinal chemistry Alkyl Titanium Flue-gas desulfurization
Zdroj:	Tetrahedron Letters. 40:5353-5356
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(99)00975-2
Popis:	The desulfurization of 1,3-bis(phenylthio)alk-1-enes with the low valent titanium species Cp 2 Ti[P(OEt) 3 ] 2 and subsequent reaction with tert -alkyl chlorides gave the terminal olefins regioselectively. The similar reactions also took place when β,γ-unsaturated thioacetals were treated successively with the titanocene(II) species and tert -alkyl chlorides. It was suggested that the present reactions proceeded via the formation of ( E )-vinyltitanium intermediate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4730032c77ea0e23090c7aed3c5c1854 https://doi.org/10.1016/s0040-4039(99)00975-2 Zobrazit plný text záznamu Full Text from ScienceDirect