Capto-dative effects measured by azo decompositions

Autor:	Alan E. Luedtke, Jack W. Timberlake, Heinz G. Viehe, Jean-Luc Bougeois, Sara Gardner, Robert Merényi, Zdenek Janousek
Rok vydání:	1988
Předmět:	chemistry.chemical_classification Azo compound Diazonium Compounds Stereochemistry Radical Organic Chemistry Biochemistry Decomposition chemistry.chemical_compound Reaction rate constant chemistry Drug Discovery Physical chemistry Chemical stability Aliphatic compound Chemical decomposition
Zdroj:	Tetrahedron Letters. 29:3379-3382
ISSN:	0040-4039
DOI:	10.1016/0040-4039(88)85167-0
Popis:	The activation parameters determined for rates of decomposition of compounds 3a-d indicate a substantial difference in free energies of activation, approximately 6 kcal mol , and can be explained on the basis of capto-dative stabilization of the incipient radicals.
Databáze:	OpenAIRE
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