Synthesis of long-chained oligo-α-aminopyridines by tandem Pd-catalyzed cross-coupling aminations and their helical dinuclear complexes

Autor:	Hasan Hasanov, Rui-Ren Wang, Gene-Hsiang Lee, Shie-Ming Peng, Uan-Kang Tan
Rok vydání:	2004
Předmět:	Coupling (electronics) Denticity Tandem Ligand Stereochemistry Chemistry Organic Chemistry Drug Discovery Protonation Biochemistry Catalysis Aminopyridines
Zdroj:	Tetrahedron Letters. 45:7765-7769
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2004.08.066
Popis:	Three novel multidentate long-chained oligo-α-aminopyridine ligands, nonapyridyloctaamine ( 1 , npoa ), decapyridylnonaamine ( 2 , dpna ), and undecapyridyldecaamine ( 3 , upda ) were synthesized successfully by tandem Pd-catalyzed cross-coupling aminations. The helical structures of protonated ligand npoa { 4 , [H4· npoa ](SO3CF3)4} and the related dinuclear complexes 5–10 were synthesized and characterized by X-ray diffractions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46fff9c4829caee7b78de26da48f5710 https://doi.org/10.1016/j.tetlet.2004.08.066 Zobrazit plný text záznamu Full Text from ScienceDirect