Sterically induced cis isomerism in an Sb(III) imido dimer; synthesis, structure and solution dynamics of [(Me2N)Sb(μ-NDipp)]2 (Dipp = 2,6-Pr2iC6H3)

Autor:	Michael A. Beswick, Alexander D. Hopkins, Christopher N. Harmer, Paul R. Raithby, Michael A. Paver, Dominic S. Wright
Rok vydání:	1998
Předmět:	Inorganic Chemistry Steric effects Crystallography chemistry.chemical_compound Stereochemistry Chemistry Dimer Materials Chemistry Proton NMR Amine gas treating Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 17:745-748
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(97)00372-0
Popis:	The reaction of [Sb(NMe2)3] with the sterically bulky amine [DippNH2] gives the unusual cis dimer [(Me2N)Sb(μ-NDipp)]2 1, containing a puckered Sb2N2 core. 1H NMR studies show that the cis conformation is retained in solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46c36f041f0810fbc43079860abcc79f https://doi.org/10.1016/s0277-5387(97)00372-0 Zobrazit plný text záznamu Full Text from ScienceDirect