Hexafluorophosphate intercalation into graphite electrode from gamma-butyrolactone solutions in activated carbon/graphite capacitors
| Autor: | Li Qi, Hongyu Wang, Masaki Yoshio, Shengfeng Tian, Gao Jichao |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Graphene Intercalation (chemistry) Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element law.invention chemistry.chemical_compound symbols.namesake chemistry law Hexafluorophosphate Propylene carbonate symbols Graphite Electrical and Electronic Engineering Physical and Theoretical Chemistry Raman spectroscopy Carbon Ethylene carbonate |
| Zdroj: | Journal of Power Sources. 297:121-126 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/j.jpowsour.2015.06.111 |
| Popis: | In our recent work, the solvent of ethylene carbonate (EC) has been found to retard the intercalation of anions into graphite electrodes. Here we demonstrate that gamma-butyrolactone (GBL) also exhibits suppressive effect on the intercalation of PF 6 − into the interlayer space between the graphene planes. The intercalation process of PF 6 − into graphite electrode from GBL has been investigated by in situ XRD, in situ Raman and EQCM. Furthermore, the effect of GBL has been compared with those of EC and propylene carbonate (PC). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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