Thermogravimetric behaviour and structure of some dithiocarbamates

Autor:	M. I. Kitovskaya, Yu. S. Lyalikov
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Crystallography Thermogravimetric analysis Group (periodic table) Experimental Finding Chemistry Thermal decomposition Structure (category theory) Organic chemistry Molecule Polymer Alkyl
Zdroj:	Journal of Thermal Analysis. 7:301-307
ISSN:	1572-8943 0368-4466
DOI:	10.1007/bf01911940
Popis:	The study of the thermogravimetric behaviour of different groups of dithiocarbamates and data on the mechanism of their thermal decomposition indicated a formula consisting of dimeric structural units for ethylene-bis-dithiocarbamates of cyclic structure. The dimeric structure concept is in good agreement with experimental data, explains the different behaviours of alkyl- and some alkylenedithiocarbamates, and also yields an explanation for the experimental finding that in the first step of thermal decomposition of the ethylene-bis-dithiocarbamates of divalent metals, one CS2 group per molecule is set free.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46bc2ab109c0693949251c1923bed303 https://doi.org/10.1007/bf01911940 Zobrazit plný text záznamu Full text from SpringerLink