Solid Solution Precursors to Gadolinia-Doped Ceria Prepared via a Low-Temperature Solution Route

Autor:	Allan J. Jacobson, Yong Bok Go
Rok vydání:	2007
Předmět:	Materials science Morphology (linguistics) General Chemical Engineering Doping Inorganic chemistry Ionic bonding General Chemistry Decomposition chemistry.chemical_compound chemistry Materials Chemistry Carbonate Formate Small particles Solid solution
Zdroj:	Chemistry of Materials. 19:4702-4709
ISSN:	1520-5002 0897-4756
Popis:	The conditions for the high-yield preparation of two crystalline solid solution precursors to high-purity gadolinia-doped ceria (GDC) powder have been systematically investigated. Cerium−gadolinium solid solution formate and carbonate precursors were obtained directly from solution in crystalline form with small particle size, and their decomposition behavior was determined. The morphology of the precursor crystals and the GDC powders obtained by their decomposition were found to be influenced by the reactants, reaction temperature, and the reaction method. The GDC powders were easily densified, and the measured ionic conductivities are comparable to the best literature data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46b6a5360449b2a746405cf74feecf87 https://doi.org/10.1021/cm071310k Zobrazit plný text záznamu