Synthesis, Crystal Structure, and Characterization of (Z)-2-(3-chlorophenyl)-N’-hydroxyacetamidine

Autor:	M. M. M. Abdoh, Neratur Krishnappagowda Lokanath, Gundibasappa Karikannar Nagaraja, Dinesha, M. Prabhuswamy, K.J. Pampa, S. Madan Kumar
Rok vydání:	2015
Předmět:	Diffraction Crystallography Chemistry Elemental analysis Intramolecular force Intermolecular force Proton NMR Molecule General Materials Science General Chemistry Crystal structure Condensed Matter Physics Monoclinic crystal system
Zdroj:	Molecular Crystals and Liquid Crystals. 606:189-198
ISSN:	1563-5287 1542-1406
Popis:	The compound (Z)-2-(3-chlorophenyl)-N’-hydroxyacetamidine, (2) was synthesized and characterized by 1H NMR, FT-IR, TGA, UV-Visible Spectra, and elemental analysis. Its molecular structure was solved by single-crystal X-ray diffraction method. The title molecule, C8H9ClN2O is crystallized in the monoclinic crystal system with the space group P21/c and with unit cell parameters a = 8.7092(4) A, b = 8.2370(4) A, c = 12.5256(6) A, β = 102.252(3)°, and Z = 4. The molecular and crystal structure of the title molecule is stabilized by an intramolecular interaction of the type N—HċċċO, and the intermolecular interactions of types N—HċċċN and O—HċċċN.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46ab8060a57391dff404d436020a5b5b https://doi.org/10.1080/15421406.2014.905087 Zobrazit plný text záznamu