Synthesis and Anti-Oxidative Properties of Poly(diphenylamine) Derivative as Lubricant Antioxidant
Autor: | Jian-Jian Zhang, Shi-Zhao Yang, Xin Xu, Li Guo, Jian-Qiang Hu |
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Rok vydání: | 2019 |
Předmět: |
Thermogravimetric analysis
Antioxidant 010405 organic chemistry General Chemical Engineering medicine.medical_treatment Diphenylamine Formaldehyde Energy Engineering and Power Technology General Chemistry 010402 general chemistry 01 natural sciences Pentaerythritol 0104 chemical sciences Styrene chemistry.chemical_compound Fuel Technology Differential scanning calorimetry chemistry Geochemistry and Petrology medicine Amine gas treating Nuclear chemistry |
Zdroj: | Petroleum Chemistry. 59:1037-1042 |
ISSN: | 1555-6239 0965-5441 |
DOI: | 10.1134/s0965544119090081 |
Popis: | The poly(diphenylamine) derivative (PDPA) as amine antioxidant was synthesized via diphenylamine, styrene, and formaldehyde. The steps of the synthesis were discussed in detail, and the structure of PDPA was fully characterized with multiple analysis techniques. Furthermore, the anti-oxidative properties of PDPA were evaluated through oxidation–corrosion tests and differential scanning calorimetry. It was found that PDPA significantly improved the oxidation stability of base oils, especially pentaerythritol ester when it was added at concentrations of only 0.5 wt % to 0.8 wt %. Thermogravimetric analysis shows that anti-oxidation behavior of PDPA is better than traditional additive p, p-dioctylphenylamine. The synthesized PDPA antioxidant is a potential alternate additive in high-temperature conditions. |
Databáze: | OpenAIRE |
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