| Popis: |
The processes which take place with the α,β-unsaturated compound 1,2,3,3-tetraphenyl-2-propen-1-one (1) under the influence of WCl6 were investigated. Special attention was paid to the low-molecular-weight products. It was established that beside polydiphenylacetylene and benzophenone also benzil, tetraphenylethylene and molecular oxygen are present in the product mixture. Their formation is explained as a result of a redistribution of the atoms connected with double bonds according to olefin metathesis (OM), carbonyl-olefin exchange reaction (COER) and reductive coupling (RC) of carbonyl compounds, accompanied by molecular oxygen evolution. The yields of products insoluble in methanol are sometimes higher than a simple stoichiometry would allow. This can be attributed to the participation of both the inner double bonds of the polymer and the low-molecular-weight products. |
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