N-Substituted Iminopyridine Arene-Ruthenium Complexes for the Regioselective Catalytic Hydration of Terminal Alkynes
| Autor: | Shaikh M. Mobin, Rohit K. Rai, Deepika Tyagi, Sanjay Kumar Singh |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Chemistry Organic Chemistry Markovnikov's rule chemistry.chemical_element Regioselectivity 010402 general chemistry Mass spectrometry 01 natural sciences Medicinal chemistry 0104 chemical sciences Catalysis Ruthenium Hydration reaction Organic chemistry High activity Single crystal |
| Zdroj: | Asian Journal of Organic Chemistry. 6:1647-1658 |
| ISSN: | 2193-5807 |
| DOI: | 10.1002/ajoc.201700396 |
| Popis: | A series of N-substituted iminopyridine ligands (L1-OH - L3-iPr) based arene-Ru(II) complexes with general formula [(η6-arene)Ru(N,N'-R")Cl]+ was synthesized and characterized by NMR, mass spectrometry, and single crystal X-ray diffraction studies. The synthesized arene-Ru(II) complexes showed high activity for the regioselective Markovnikov hydration of a range of aromatic and aliphatic terminal alkynes and produced moderate to good yields of corresponding methyl ketones. Moreover, the studied Ru(II) catalysts showed good recyclability. Mechanistic studies of the Ru(II) catalyzed hydration reaction was investigated in detail by performing mass experiments and control experiments followed by the identification of crucial Ru(II)-alkyne and Ru(II)-vinyl organometallic species. |
| Databáze: | OpenAIRE |
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