Redox extractions from molten alkali-metal cyanides. Part 1. Mechanism for extractions with liquid zinc alloys

Autor:	Karel F. Fouché, Johannes G. V. Lessing, Thomas T. Retief
Rok vydání:	1977
Předmět:	Zinc alloys Binary alloy Extraction (chemistry) Inorganic chemistry General Chemistry Alkali metal Redox Metal chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Zinc cyanide Eutectic system
Zdroj:	J. Chem. Soc., Dalton Trans.. :2020-2024
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9770002020
Popis:	The distribution of Rh, Ir, Ru and Cu between a 9% zinc cyanide solution in molten eutectic KCN–NaCN and a liquid binary alloy of Zn with Bi or Sn was determined at 530 °C. The results fit an exchange-type extraction mechanism e.g. [graphic omitted] The activity-coefficient ratios of the extracted metal in the components of the binary alloy phases can also be calculated from the distribution data.
Databáze:	OpenAIRE
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