ChemInform Abstract: Reactions of Oximes with Thianthrene Cation Radical in Nitrile Solvents. Cycloaddition to Form Oxadiazoles and Deoxygenation to Form Nitriles

Autor:	Henry J. Shine, Shishue Chiou, A. K. M. M. Hoque
Rok vydání:	1990
Předmět:	chemistry.chemical_compound Perchlorate Cation radical chemistry Nitrile General Medicine Acetonitrile Thianthrene Oxime Medicinal chemistry Deoxygenation Cycloaddition
Zdroj:	ChemInform. 21
ISSN:	0931-7597
DOI:	10.1002/chin.199038083
Popis:	Reactions of eight oximes, RCH=NOH (1a, R=C 6 H 5 ; 1b, R=4-CH 3 C 6 H 4 ; 1c, R=4-NO 2 C 6 H 4 ; 1d, R=4-CH 3 OC 6 H 4 ; 1e, R=2-CH 3 OC 6 H 4 ; 1f, R=1-naphthyl; 1g, R=C 5 H 11 ; 1h, R=C 4 H 9 ) with thianthrene cation radical perchlorate (Th •+ ClO 4 − ) in acetonitrile under argon were studied. The major product from the oxime in all cases, but of 1d, was the nitrile, RCN
Databáze:	OpenAIRE
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