Length enhancement of thermoelectric effects in DNA duplex chains due to quantum interferences

Autor: Yushen Liu, Xue-Mei Wu, Xue-Feng Wang, Yao-Jun Dong
Rok vydání: 2015
Předmět:
Zdroj: Organic Electronics. 26:176-180
ISSN: 1566-1199
DOI: 10.1016/j.orgel.2015.07.043
Popis: The thermoelectric performance of DNA duplex chains (G:C)–(T:A)n–(G:C)3 is studied by a tight-binding ladder model. The quantum interferences due to intra- and inter-strand couplings can greatly enhance the thermopower effect in long systems. The peak value of Seebeck coefficient increases exponentially with n while the charge transfer rate remains almost constant for n > 3 as previously measured. Big figure of merit (ZT) might be available for large n. This result is applicable to other wire molecules having similar structure.
Databáze: OpenAIRE