Study of Americium Behavior in chloride melts in presence of oxygen

Autor:	V.S. Mityaev, A.V. Bychkov, A.L. Bovet, N.P. Borodina, V.V Smolenski, A.G. Ossipenko
Rok vydání:	2002
Předmět:	Nuclear and High Energy Physics Chemistry Inorganic chemistry Potentiometric titration Ionic bonding chemistry.chemical_element Americium Alkali metal Chloride Chemical reaction Electrochemical cell Nuclear Energy and Engineering medicine Eutectic system medicine.drug
Zdroj:	Journal of Nuclear Science and Technology. 39:592-594
ISSN:	1881-1248 0022-3131
Popis:	The americium cations-oxygen anions interaction was investigated the by potentiometric titration method using an electrochemical cell with two platinum-oxygen electrodes having a solid-electrolytic membrane in the alkaline metals molten chlorides (NaCl-KCl-CsCl and NaCl-CsCl eutectic mixtures, NaCl-KCl equimolar mixture) in the temperature range of 550-700 C depending on the medium oxo-acidity. Assumptions were stated of the ionic and phase composition of the produced high-temperature compounds and chemical reactions proceeding in the melts. The main thermodynamic values were calculated for the produced americium oxide and oxy-chloride.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::466f2f707ac53149bb38783d5a9a12e6 https://doi.org/10.1080/00223131.2002.10875537 Zobrazit plný text záznamu