Preparation of a single-phase solid electrolyte La1 − x Sr x Ga1 − y Mg y O3 − (x + y)/2 by self-propagating high-temperature synthesis
| Autor: | A. A. Korneva, A. S. Lipilin, A. V. Nikonov, S. N. Shkerin, Vladimir N. Krasil’nikov, Olga I. Gyrdasova |
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| Rok vydání: | 2011 |
| Předmět: |
Materials science
Annealing (metallurgy) Scanning electron microscope Materials Science (miscellaneous) Inorganic chemistry Self-propagating high-temperature synthesis chemistry.chemical_element Electrolyte Grain size Inorganic Chemistry chemistry.chemical_compound chemistry Chemical engineering Lanthanum Physical and Theoretical Chemistry Gallium Ethylene glycol |
| Zdroj: | Russian Journal of Inorganic Chemistry. 56:999-1003 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | Highly dispersed single-phase powders described as La0.88Sr0.12Ga0.82Mg0.18O2.85 were prepared using a method based on the principles of self-propagating high-temperature synthesis (SHS). Lanthanum, strontium, gallium, and magnesium nitrates were used in the SHS as “oxidants”, and ethylene glycol was used as the reducing agent. The initial reaction mixture was liquid. According to X-ray diffraction and scanning electron microscopy data, the sample becomes a single phase after annealing of the primary SHS product at 1200°C, which is substantially lower than in other synthetic methods. Using so active powders (grain size of about 100–130 nm), it is possible to reduce the temperature of the final annealing of the ceramics to 1275°C, which gives rise to single-phase finely dispersed ceramics having specific properties. |
| Databáze: | OpenAIRE |
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