Characterization of a Reactive Rh2 Nitrenoid by Crystalline Matrix Isolation

Autor:	David Powers, Joseph Reibenspies, Yu-Sheng Chen, Anuvab Das
Rok vydání:	2019
DOI:	10.26434/chemrxiv.9273395
Popis:	Here we report the first X-ray crystal structure of a reactive Rh2 nitrenoid, enabled by N2 elimination from an organic azide ligand within a single-crystal matrix. The resulting high-resolution data set demonstrates a long Rh–N bond, consistent with a triplet electronic structure. The demonstration of facile access to reactive metal nitrenoids within a crystalline matrix provides a platform for structural characterization of the elusive transient species at the heart of C–H functionalization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::46696204e491534fe14a27118097f767 https://doi.org/10.26434/chemrxiv.9273395 Zobrazit plný text záznamu