Crystal structure of 6-(1-adamantyl)-3-cyanopyridine-2(1H)-selenone

Autor:	Yu. A. Sharanin, V. N. Nesterov, Yu. T. Struchkov, V. P. Litvinov, V. E. Shklover, E. E. Apenova, V. Yu. Mortikov
Rok vydání:	1988
Předmět:	chemistry.chemical_classification Diffraction Crystallography Double bond chemistry Hydrogen bond Product (mathematics) Sodium Molecule chemistry.chemical_element General Chemistry Crystal structure
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:397-399
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00957459
Popis:	1. An x-ray diffraction structural study showed that the product of the reaction of sodium 3-(1-adamantyl)-3-oxo-1-propen-1-olate with cyanoselenoacetamide is 6-(1-adamantyl)-3-cyanopyridine-2(1H) -selenone. The length of the C=Se double bond is 1.80(1) a. 2. 6-(1-Adamantyl)-3-cyanopyridine-2(1H)-selenone crystallizes from the reaction medium as a monohydrate. The selenone molecule is connected to the water molecule by N-H...O and O-H...Se hydrogen bonds.
Databáze:	OpenAIRE
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